Get Activating Unreactive Substrates: The Role of Secondary PDF

By Carsten Bolm, F. Ekkehardt Hahn

ISBN-10: 3527318232

ISBN-13: 9783527318230

ISBN-10: 3527625461

ISBN-13: 9783527625468

Using secondary interactions for the activation of non-reactive substrates constitutes a brand new and glossy strategy in catalysis.
this primary accomplished therapy of this crucial examine box covers the complete box and divulges the hyperlinks among a few of the chemical disciplines. It hence adopts an interdisciplinary process, making it of curiosity to the complete chemical community.
A needs to for natural, inorganic, catalytic and complicated chemists, in addition to these operating with/on organometallics.Content:
Chapter 1 Chemistry of Metalated box Molecules (pages 1–15): Berthold Kersting
Chapter 2 The Chemistry of Superbasic Guanidines (pages 17–37): Jorg Sundermeyer, Volker Raab, Ekatarina Gaoutchenova, Udo Garrelts, Nuri Abacilar and Klaus Harms
Chapter three Iron Complexes and Dioxygen Activation (pages 39–51): Thomas Nebe, Jing?Yuan Xu and Siegfried Schindler
Chapter four Tuning of buildings and homes of Bispidine Complexes (pages 53–63): Peter Comba and Marion Kerscher
Chapter five Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for functions in Homogeneous Catalysis (pages 65–88): Anna?Katharina Pleier, Yu solar, Anett Schubert, Dirk Zabel, Claudia may possibly, Andreas Reis, Gotthelf Wolmershauser and Werner R. Thiel
Chapter 6 Square?Pyramidal Coordinated Phosphine Iron Fragments: A story of the unforeseen (pages 89–102): Andreas Grohmann and Stephan Kohl
Chapter 7 Regioselective Catalytic task of Complexes with NH, NR?Substituted Heterocyclic Carbene Ligands (pages 103–122): Siegfried R. Waldvogel, Anke Spurg and Prof. Dr. F. Ekkehardt Hahn
Chapter eight Functionalized Cycloheptatrienyl?Cyclopentadienyl Sandwich Complexes as construction Blocks in Metallo?Supramolecular Chemistry (pages 123–146): Matthias Tamm
Chapter nine Monosaccharide Ligands in Organotitanium and Organozirconium Chemistry (pages 147–164): Peter Kitaev, Daniela Zeysing and Jurgen Heck
Chapter 10 Reactions of C?F Bonds with Titanocene and Zirconocene: From Secondary interplay through Bond Cleavage to Catalysis (pages 165–182): Uwe Rosenthal, Vladimir V. Burlakov, Perdita Arndt, Anke Spannenberg, Ulrike Jager?Fiedler, Marcus Klahn and Marko Hapke
Chapter eleven Bisazines within the Coordination Sphere of Early Transition Metals (pages 183–207): Ruediger Beckhaus
Chapter 12 Bifunctional Molecular structures with Pendant Bis(pentafluorophenyl)boryl teams: From Intramolecular CH?Activation to Heterolytic Dihydrogen Splitting (pages 209–230): Michael Hill, Christoph Herrmann, Patrick Spies, Gerald Kehr, Klaus Bergander, Roland Frohlich and Gerhard Erker
Chapter thirteen Ruthenium?Containing Polyoxotungstates: constitution and Redox task (pages 231–243): Ulrich Kortz
Chapter 14 From NO to Peroxide Activation by way of version Iron(III) Complexes (pages 245–272): Alicja Franke, Natalya Hessenauer?Ilicheva, Joo?Eun Jee and Rudi van Eldik
Chapter 15 artificial Nitrogen Fixation with Molybdenum and Tungsten Phosphine Complexes: New advancements (pages 273–296): Gerald Stephan and Felix Tuczek
Chapter sixteen Directed C?H Functionalizations (pages 297–312): Prof. Dr. Carsten Bolm
Chapter 17 improvement of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide (pages 313–337): guy relatives Tse, Bianca Bitterlich and Matthias Beller
Chapter 18 Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding websites (pages 339–348): Caroline A. Schall, Michael Seitz, Anja Kaiser and Oliver Reiser
Chapter 19 Flavin Photocatalysts with Substrate Binding websites (pages 349–358): Harald Schmaderer, Jiri Svoboda and Burkhard Konig
Chapter 20 New Catalytic Cu?, Pd? and Stoichiometric Mg?, Zn?Mediated Bond Activations (pages 359–377): Tobias Thaler, Hongjun Ren, Nina Gommermann, Giuliano C. Clososki, Christoph J. Rohbogner, Stefan H. Wunderlich and Paul Knochel
Chapter 21 From Cobalt(II)?Activated Molecular Oxygen to Hydroxymethyl?Substituted Tetrahydrofurans (pages 379–396): Barbara Menendez Perez, Dominik Schuch and Jens Hartung
Chapter 22 Regiodivergent Epoxide commencing (pages 397–409): Andreas Gansauer, Florian Keller, Chun?An Fan and Peter Karbaum
Chapter 23 Supramolecular packing containers: Host?Guest Chemistry and Reactivity (pages 411–425): Markus Albrecht
Chapter 24 Self?Assembly of Dinuclear Helical Metallosupramolecular Coordination Compounds (pages 427–446): Ulf Kiehne, Jens Bunzen and Arne Lutzen

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Extra resources for Activating Unreactive Substrates: The Role of Secondary Interactions

Example text

Most interestingly, peroxonitrite does not rearrange to nitrate but decomposes to dioxygen and an O-nitrito complex. 6) [31]. 9) have never been isolated and structurally characterized. Therefore we follow the concept of generating these intermediates within the sterically demanding ligand regime of these guanidine tripod ligands. 6 Modeling copper-monooxygenase C-H hydroxylation and peroxonitrite formation and decomposition. never been detected, different synthetic routes for their synthesis, namely the reactions of [(TMG3tren)Cu]þ , [(DMEG3tren)Cu]þ and [(HPG3tren)Cu]þ with TsN3, [PhI(NTs)]x and [PhIO]x in MeCN, were chosen.

Roth [30], while K. Karlin offered his expertise in well-designed reactivity studies on the superoxo complex. Reactivity is relevant as end-on copper complexes play a role in nature’s enzymatic CH hydroxylation reactions. At the same time, when we proposed the existence of this end-on superoxo complex, Prigge et al. presented an unusual end-on Cu-O2 complex observed in an XRD structure of pepdidylglycine-a-hydroxylating monooxygenase [33] refined to 185 pm. This important finding supports the view that an end-on superoxo mono copper site is the precatalytic species in the a-hydroxylation of CÀH bonds by this enzyme.

Despite the fact that the active coordination site L0 is deeply buried in the center of the molecules, it is readily accessible for a wide range of exogenous guest molecules. A large number of crystal structure determinations have provided insights into the binding modes of the coligands. These sense the size and form of the binding pocket of the [M2L]2 þ fragments, as indicated by distinctive binding modes and unusual conformations. The use of the N-alkylated macrocycles in place of the unmodified analogs influences many properties of the binuclear complexes, including color, molecular and electronic structure, hydrogen bonding interactions, redox potential, complex stability, and ground spin-state.

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Activating Unreactive Substrates: The Role of Secondary Interactions by Carsten Bolm, F. Ekkehardt Hahn


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